少点错误 08月27日
理解麦克斯韦妖:信息与热力学第二定律
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文章探讨了经典的麦克斯韦妖思想实验及其与热力学第二定律的关系。传统的观点认为,妖精需要存储信息,而信息具有熵的“成本”,以此来解释其对第二定律的潜在违反。然而,作者提出了“做-散度定理”(Do-Divergence Theorem),从代理(agent)的角度,将妖精的行为分解为观察和行动。该定理表明,妖精的行动与观察之间的互信息量至少需要达到某个阈值,才能实现对气体的分类。这一定理为理解信息如何影响物理系统提供了新的视角,并试图摆脱对统计力学和物理熵的依赖,转向更通用的代理模型。

💡 **麦克斯韦妖的经典设定与熵增困境**:文章以麦克斯韦妖思想实验开篇,描述了一个能够通过开关隔板控制分子进出的妖精,其潜在能力是聚集气体于容器一侧,从而降低熵,似乎违反了热力学第二定律。这引发了对信息在其中作用的长期讨论。

⚖️ **从统计力学到代理理论的理论演进**:文章批评了Landauer关于信息熵成本的传统解释,认为它循环论证且过于依赖物理熵。为解决此问题,提出了“做-散度定理”(Do-Divergence Theorem),将问题框架从统计力学转向更普适的嵌入式代理(embedded agency)模型,关注代理的观察(O)和行动(A)及其策略(π)。

📏 **做-散度定理的核心内容与应用**:该定理指出,系统状态X的分布变化(衡量标准为KL散度)与其在“盲操作”(即行动独立于观察)下的分布之差,小于等于行动(A)与观察(O)之间的互信息量(MI(A;O))。在麦克斯韦妖的案例中,这意味着妖精的分类行动与对分子状态的观察之间,至少需要n比特的互信息量,才能实现n个分子的有效分离,并将熵减与信息量联系起来。

Published on August 26, 2025 5:07 PM GMT

Let’s start with the classic Maxwell’s Demon setup.

 

We have a container of gas, i.e. a bunch of molecules bouncing around. Down the middle of the container is a wall with a tiny door in it, which can be opened or closed by a little demon who likes to mess with thermodynamics researchers. Maxwell[1] imagined that the little demon could, in principle, open the door whenever a molecule flew toward it from the left, and close the door whenever a molecule flew toward it from the right, so that eventually all the molecules would be gathered on the right side. That would compress the gas, and someone could then extract energy by allowing the gas to re-expand into its original state. Energy would be conserved by this whole process, since the gas would end up cooler in proportion to the energy extracted, but it would violate the Second Law of Thermodynamics - i.e. entropy would go down.

Landauer famously proposed to “fix” this apparent loophole in the Second Law by accounting for the information which the demon would need to store, in order to know when to open and close the door. Each bit of information has a minimal entropic “cost”, in Landauer’s formulation. This sure seems to be correct in practice, but it’s unsatisfying: as has been pointed out before[2], Landauer derived his bit-cost by assuming that the Second Law holds and then asking what bit cost was needed to make it work. This really seems like the sort of thing where we should be able to get a mathematical theorem, from first principles, rather than assuming.

Also, Landauer’s approach is a bit weird for embedded agency purposes. It feels like almost the right tool, but not quite; it’s not really framed in terms of canonical parts-of-an-agent, like e.g. observations and actions and policy. And it’s too dependent on physical entropy, which itself grounds out in the reversibility of low-level physics. Ideally, we’d like something more agnostic to the underlying physics, so that e.g. we can apply it directly even to high-level systems with irreversible dynamics.

So we’d like a theorem, and we’d like it to be more directly oriented toward embedded agency rather than stat mech. To that end, we present the Do-Divergence Theorem.

Rather than focus on “memory”, we’ll take a more agentic frame, and talk about the demon’s observations () and actions (). The observations are the inputs to the demon’s decisions (presumably measurements of the initial state of the molecules); the actions are whether the door is open or closed at each time. Further using agentic language, the demon’s policy  specifies how actions are chosen as a function of observation:  is a distribution from which the action  is sampled. Downstream, the actions and observations together cause some outcome , the final state of the molecules.

 

Now for the key idea: we’re going to compare the distribution of states  achieved by the demon with policy , to the distribution of states  which would be achieved by the demon if it took the same distribution of actions completely independent of its observations - i.e. if it just blindly tried to sort the molecules without looking at them.

We express the “blind sorting” model as a do-operation on the causal diagram above: , below, indicates that the demon samples an action from  independent of its observations . So, under the model , we have 

… in contrast to the original model, under which

To compare the distribution achieved by the demon to the “blind sorting” distribution, we’ll use KL-divergence; more on what that looks like after the theorem.

Now for the theorem itself:

Where  is the mutual information between actions and observations. Proof:

Now let’s unpack what the theorem means, when applied to Maxwell’s Demon.

When the demon takes actions independent of observations (i.e. independent of the state of the molecules), molecules are just as likely to move from left container to right container as from right to left. So, the distribution should end up roughly uniform across both sides, as is normal for a single connected container of gas.

On the other hand, if the demon perfectly sorts the molecules on to the right side, then the molecules end up roughly uniform on only one side of the container.

The KL-divergence between these distributions is then roughly

So: with n molecules, the KL divergence between the two distributions is , i.e.  bits, as one might intuitively guess. In a case like this, the KL divergence is just the entropy change.

The do-divergence theorem therefore says that the demon’s actions must have at least n bits of mutual information with its observations of the molecule states, in order to sort the molecules. All the change in entropy of the system must be balanced by mutual information between the demon’s actions and observations.

  1. ^

    yes, same guy as the electromagnetic laws

  2. ^


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麦克斯韦妖 热力学第二定律 信息熵 做-散度定理 代理理论 Maxwell's Demon Second Law of Thermodynamics Information Entropy Do-Divergence Theorem Agent Theory
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